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Materials Science and Engineering, University of Michigan

  MSE / People / Faculty / Richard Laine

Articles

  1. M. Kim, R.M. Laine, "Sintering behavior of ZrO2/-Al2O3 core shell nanopowders," J. Am. Ceram. Soc. in press, (2010).
  2. B. Weidenhof, M. Reiser, K. Stöwe, W. F. Maier, M. Kim, J. Azurdia, E. Gulari, E. Sekkers, A. Barks, and R. M. Laine, "High Throughput Screening of Nanoparticle Catalysts Made by Flame Spray Pyrolysis as Hydrocarbon/NO Oxidation Catalysts; Active, Pt free catalysts," J. Am. Chem. Soc. , Vol. 131, pp. 9207-19 (2009).
  3. M. Kim, R. M. Laine, "A one-step synthesis of core-shell (Ce0.7Zr0.3O2)x(Al2O3)1-x [(Ce0.7Zr0.3O2)@Al2O3] nanopowders via liquid-feed flame spray pyrolysis (LF-FSP)," J. Am. Chem. Soc., Vol. 131, pp. 9220-9 (2009).
  4. . Sulaiman, A. Bhaskar, J. Zhang, R. Guda, T. Goodson III, R.M. Laine, "Molecules with perfect cubic symmetry as nanobuilding blocks for 3-D assemblies. Elaboration of octavinylsilsesquioxane. Unusual luminescence shifts may indicate extended conjugation involving the silsesquioxane core," Chem Mater. , Vol. 20, pp. 5563 – 5573 (2008).
  5. I. Hasegawa, R. M. Laine, M. Z. Asuncion, N. Takamura, "Facile synthesis of polyhedral silsesquioxane anions and uses thereof," U.S. Patent 7,576,169 Sept., 2008, (2008).
  6. J. A. Azurdia, A. McCrum, R.M. Laine, "Systematic Synthesis of Mixed Metal Oxides in NiO-Co3O4, NiO-MoO3, and NiO-CuO Systems via Liquid Feed-Flame Spray Pyrolysis," Materials Chem. , Vol. 18, pp. 3249-3258 (2008).
  7. M. Kim, T.R. Hinklin, R.M. Laine, "Core−shell Nanostructured Nanopowders along (CeOx)x(Al2O3)1−x Tie-Line by Liquid-Feed Flame Spray Pyrolysis (LF-FSP)," Chem. Mater., Vol. 20, pp. 5154-5162 (2008).
  8. M.F. Roll, M.Z. Asuncion, J. Kampf, R.M. Laine, "para-Octaiodophenylsilses-quioxane, [p-IC6H4SiO1.5]8, a nearly perfect nanobuilding block," ACS Nano , Vol. 2, pp. 320-26 (2008).
  9. M.Z. Asuncion, M.F. Roll, Richard M. Laine, "Octaalkynylsilsesquioxanes, Sea Urchin Molecular connectors for 3-D-Nanostructures," Macromolecules, Vol. 41, pp. 8047-8052 (2008).
  10. R. M. Laine, T.R. Hinklin, J. Azurdia, M. Kim, J.C. Marchal, S. Kumar, "Finding Spinel in All the Wrong Places," Adv. Mater. , Vol. 20, pp. 1373-75 (2008).
  11. R.M. Laine, D. Bartz, D.J. Krug, V. Popova, M.Z. Asuncion , "Bi- and trifunctional silsesquioxanes for novel coating applications," filed June, 2007. PTO filed Aug. 2008., (2008).
  12. R.M. Laine, M. Roll, M. Asuncion, S. Sulaiman, V. Popova, D. Bartz, D.J. Krug, P. H. Mutin, "Perfect and Nearly Perfect Silsesquioxane (SQs) Nanoconstruction Sites and Janus SQs," J. Sol-Gel Sci. Tech. , Vol. 46, pp. 335-347 (2008).
  13. S.-G. Kim, S. Sulaiman, D. Fargier, R.M. Laine, "Simple syntheses of octaphenyloctasilsesquoxane and polyphenylsilsesquioxane. Starting point for aromatic nanocomposites with complete control of physical and chemical properties at nanometer length scales," in Materials Syntheses. A Practical Guide, pp. 179-182,Eds. U. Schubert, N. Hüsing, R. Laine, Springer-Verlag, Wein (2008).
  14. T. R. Hinklin, S. C. Rand and R. M. Laine, "Transparent, polycrystalline upconverting nanoceramics. Towards 3-D displays," Adv. Mater. , Vol. 20, pp. 1270-1273 (2008).
  15. T.R. Hinklin, R.M. Laine, "Synthesis of metastable phases in the Magnesium Spinel-Alumina System," Chem. Mater., Vol. 20, pp. 553-558 (2008).
  16. B. Li, S. L. Oliveira, S. C. Rand, J.A. Azurdia, T. Hinklin, J. C. Marchal, R.M. Laine, "Ultraviolet emission and Fano resonance in doped nano-alumina," J. Appl. Physics, Vol. 101, pp. 053534 (2007).
  17. B. Li, T. Hinklin, R. Laine, S. Rand, "Ultraviolet nanophosphors," Journal of Luminescence , Vol. 122-3, pp. 345-7 (2007).
  18. C. Brick, E. R. Chan, S.C. Glotzer, D.C. Martin, R.M. Laine, "Self-lubricating nano ball bearings," Adv. Mater. , Vol. 19, pp. 80-2 (2007).
  19. M. Kim, R.M. Laine, "Combinatorial processing of mixed-metal oxide nanopowders along the ZrO2-Al2O3 tie line using liquid-feed flame spray pyrolysis (LF-FSP)," J. Ceramic Processing Research, Vol. 8, pp. 129-36 (2007).
  20. M. Wang, R.M. Laine, "UV-Absorbing Coatings and Methods of Making Same," filed by Guardian Industries. U.S. Patent 7,288,283 October 30, 2007, (2007).
  21. M. Z. Asuncion, R.M. Laine, "Silsesquioxane Barrier Materials," Macromolecules, Vol. 40, pp. 555-62 (2007).
  22. N. Takamura, L. Viculis, R.M. Laine , "A completely discontinuous organic/inorganic hybrid nanocomposite based on reactions of [HMe2SiOSiO1.5]8 with vinylcyclohexene," International Polymer , Vol. 56, pp. 1378-1391 (2007).
  23. J.A. Azurdia, J.C. Marchal, P. Shea, H. Sun, X. Q. Pan, R.M. Laine, "Liquid-feed flame spray pyrolysis (LF-FSP) as a method of producing mixed-metal oxide nanopowders of potential interest as catalytic materials. Nanopowders along the NiO-Al2O3 tie-line including (NiO)0.22(Al2O3)0.78, a new inverse spinel composition.," Chem. Mater. , Vol. 18, pp. 731-9 (2006).
  24. J.A. Azurdia, J.C. Marchal, R.M. Laine, "Combinatorial processing of mixed-metal oxide nanopowders along the Co3O4-Al2O3 tie line using liquid-feed flame spray pyrolysis (LF-FSP)," J. Am. Ceram. Soc., Vol. 89, pp. 2749-56 (2006).
  25. K. Takahashi, S. Sulaiman, J.M. Katzenstein, S. Snoblen, R.M. Laine, "New Aminophenylsilsesquioxanes, Synthesis, Properties and Epoxy Nanocomposites," Australian J. Chem. , Vol. 59, pp. 564-70 (2006).
  26. R.M. Laine, J.C. Marchal, H.P. Sun, X.Q. Pan, "Nano--Al2O3 by liquid-feed flame spray pyrolysis (LF-FSP) of nano-transition aluminas," Nature Materials , Vol. 5, pp. 710-2 (2006).
  27. S. Sulaiman, C.M. Brick, C.M. De Sana, J.M. Katzenstein, R.M. Laine, R.A. Basheer, "Tailoring the Global Properties of Nanocomposites. Epoxy Resins with Very Low Coefficients of Thermal Expansion," Macromolecules, Vol. 39, pp. 5167-9 (2006).
  28. A. Sellinger, R. Tamaki, R.M. Laine, K. Ueno, H. Tanabe, E. Williams, G.E. Jabbour, "Solution processable nanocomposites based on silsesquioxane cores for use in organic light emitting diodes (OLEDs)," Chem. Comm., pp. 3700 –02 (2005).
  29. C. M. Brick, R. Tamaki, S-G. Kim, M. Asuncion, M. Roll, T. Nemoto, R.M. Laine, "Spherical, Polyfunctional Molecules Using Polybromooctaphenylsilsesquioxanes as Nanoconstruction Sites," Macromol., Vol. 38, pp. 4655-60 (2005).
  30. C.M. Brick, Y. Ouchi, Y. Chujo, R.M. Laine, "bust Polyaromatic Octasilsesquioxanes from Polybromophenylsilsesquioxanes, BrxOPS, via Suzuki Coupling," Macromol., Vol. 38, pp. 4661-5 (2005).
  31. I. Hasegawa, R.M. Laine, M. Asuncion, N. Takamura, "Facile Synthesis of the Cubeoctameric Silicate Anion, Si8O208-, its dimethylsilyl derivative, Si8O20[Si(CH3)2H]8 and certain derivatives therefrom," U.S. Patent Application publication, Vol. 0142054, June 30, (2005).
  32. I. Hasegawa, R.M. Laine, M. Asuncion, N. Takamura, "Facile Synthesis of the Cubeoctameric Silicate Anion, Si8O208-, its dimethylsilyl derivative, Si8O20[Si(CH3)2H]8 and certain derivatives therefrom," U.S. Patent Application publication, 2005/0142054, June 30, 2005, (2005).
  33. M.D. Stewart, J.T. Wetzel, G.M. Schmid, F. Palmieri, E. Thompson, E.K. Kim, D. Wang, K. Sotodoeh, K. Jen, S.C. Johnson, J. Hao, M.D. Dickey, Y. Nishimura, R.M. Laine, D.J. Resnick, C.G. Willson, "Proc. SPIE," -Int. Soc. Opt. Eng. , Vol. 5751, pp. 219 (2005).
  34. M.Z. Asuncion, I. Hasegawa, J. Kampf, R.M. Laine, "The selective dissolution of rice hull ash to form [OSiO1.5]8[R4N]8 (R = Me, CH2CH2OH) octasilicates. Basic nanobuilding blocks and possible models of intermediates formed during biosilification processes," Materials Chemistry , Vol. 15, pp. 2114-21 (2005).
  35. R. Basheer, C. Brick, R.M. Laine, S. Sulaimann, C. M. DeSana, "Flip Chip system with organic/inorganic underfill composition," Filed November 4, 2005. U.S. Patent 7,332,822, (2005).
  36. R.M. Laine, "Nano-building blocks based on the [OSiO1.5]8 silsesquioxanes," J. Mater. Chem., Vol. 15, pp. 3725 – 44 (2005).
  37. R.M. Laine, J. Marchal, H.J. Sun, X.Q. Pan, "A new Y3Al5O12 phase produced by liquid-feed flame spray pyrolysis (LF-FSP)," Adv. Mater., Vol. 17, pp. 830-33 (2005).
  38. R.M. Laine, J. Marchal, J. Azurdia, R. Rennesund, "Liquid Feed Flame Spray Modification of Nanoparticles," Application number: 11/066,822 Publication number: US 2006/0087062 A1 Filing date: Feb 25, 2005 to issue, (2005).
  39. S.G. Kim, J. Choi, R. Tamaki, R.M. Laine, "Synthesis of amino-containing oligophenylsilsesquoixanes," Polymer, Vol. 46, pp. 4514-4524 (2005).
  40. J. Choi, A.F. Yee, R.M. Laine, "Toughening of cubic silsesquioxane epoxy nanocomposites using core shell rubber particles; a three component hybrid system," Macromol., Vol. 37, pp. 3267-76 (2004).
  41. J. Marchal, T. Hinklin, R. Baranwal, T. Johns, and R. M. Laine, "Yttrium aluminum garnet nanopowders by flame spray pyrolysis," Chem. Mater. , Vol. 16, pp. 822-831 (2004).
  42. R.M. Laine, J. Marchal, S. Kim, J. Azurdia, M. Kim, "Liquid-Feed Flame Spray Pyrolysis of Single and Mixed Phase Mixed-Metal Oxide Nanopowders," in Ceramic Nanomaterials and Nanotechnology III, S. Lu, M.Z. Hu, Y. Gogotsi eds, Ceramic Transactions, Vol. 159, pp. 27 (2004).
  43. S. Kim, J.J. Gislason, R.W. Morton, X. Pan, H. Sun, R.M. Laine, "Liquid-Feed Flame Spray Pyrolysis of Nanopowders in the Alumina-Titania System," Chem. Mater. , Vol. 16, pp. 2336-43 (2004).
  44. S.M. Redmond, G.L. Armstrong, H.-Y. Chan, E. Mattson, A. Mock, B. Li, J.R. Potts, M. Cui, S.C. Rand, S.L. Oliveira, J. Marchal, T. Hinklin, R.M. Laine, "Electrical generation of stationary light in random scattering media," J. Opt. Soc. Am. B, Vol. 21, pp. 214-22 (2004).
  45. T. Hinklin, B. Toury, C. Gervais, F. Babonneau, J.J. Gislason, R.W. Morton, R.M. Laine, "Liquid-Feed Flame Spray Pyrolytic Synthesis of Nanoalumina Powders," Chem. Mater. , Vol. 16, pp. 21-30 (2004).
  46. A. Sellinger and R. M. Laine, "Organic-Inorganic Hybrid Light Emitting Devices (HLED)," U.S. Patent, 6,517,958, Feb. 11, 2003, (2003).
  47. A.C. Sutorik, R.M. Laine, J. Marchal, T. Johns, T. Hinklin, "Mixed-metal oxide particles by liquid feed-flame spray pyrolysis of oxide precursors in oxygenated solvents," WO03070640 issued 2003-08-28. U.S. Patent issued, (2003).
  48. G. Berger, R.M. Laine, J. Azurdia, "Up and down converting nanophosphors for multiplex tagging of materials processed or used in harsh environments," Application number: 10/723,709 Publication number: US 2005/0112360 A1 Filing date: Nov 26, 2003, (2003).
  49. J. Choi, R. Tamaki, S.G. Kim, R.M. Laine, "Organic/Inorganic Imide Nanocomposites from Aminophenylsilsesquioxanes," Chem. Mater. , Vol. 15, pp. 3365 – 3375 (2003).
  50. Jiwon Choi, Albert F. Yee, and Richard M. Laine, "Organic/Inorganic Hybrid Composites from Cubic Silsesquioxanes. Epoxy Resins of Octa(dimethylsiloxy-ethylcyclohexylepoxide) Silsesquioxane," Macromolecules , Vol. 15, pp. 5666 – 82 (2003).
  51. R. Tamaki, J. Choi, R.M. Laine , "A Polyimide Nanocomposite from Octa(aminophenyl)-silsesquioxane," Chem. Materials , Vol. 15, pp. 793-7 (2003).
  52. B. Li, G. Williams, S.C. Rand, T. Hinklin and R.M. Laine, "Continuous-wave ultraviolet laser action in strongly scattering Nd-doped alumina," Optics Lett. , Vol. 27, pp. 394-6 (2002).
  53. G. Williams, S.C. Rand, T. Hinklin, R.M. Laine, "Laser action in strongly scattering rare-earth-doped dielectric nanophosphors," Phys. Rev. A. , Vol. 65, pp. 013807 (2002).
  54. R.M. Laine, R. Tamaki, J. Choi, "Well-defined nanosized building blocks for organic/inorganic nanocomposites," WO 02/100867 A1 Dec. 19, 2002, (2002).
  55. S. Li, H. Feindt, A.C. Sutorik, M.S. Baliat, R.M. Laine, R.S. Niedbala, "Synthesis and Characterization of Y2O2S: Yb3+, Er3+, Up-Converting Nanophosphors," in Nanoscience and Nanotechnology in Perspective, Tsinghua Press, Issue June, pp. 221-33 (2002).
  56. C. L. Soles, E. K. Lin, W-L. Wu, C. Zhang, and R. M. Laine, "Structural Evolution of Silsesquioxane-based Organic/Inorganic Nanocomposite Networks," in Organic/Inorganic Hybrid Materials--2000, MRS Symp. Ser., Vol. 628, pp. CC4.2.1-6, R.M. Laine, C. Sanchez, and C.J. Brinker, eds. Mater. Res. Soc. (2001).
  57. C. Zhang, T.J. Bunning, R.M. Laine, "Synthesis and Characterization of Liquid Crystalline (LC) Silsesquioxanes," Chem. of Mater., Vol. 13, pp. 3653-62 (2001).
  58. J. Choi, J. Harcup, A.F. Yee, Q. Zhu, R.M. Laine, "Organic/inorganic hybrid composites from cubic silsesquioxanes," J. Am. Chem. Soc. , Vol. 123, pp. 11420-30 (2001).
  59. R. Baranwal, M. P. Villar, R. Garcia and R. M. Laine, "Synthesis, Characterization, and Sintering Behavior of Nano-mullite Powder and Powder Compacts," J. Am. Ceram. Soc. , Vol. 84, pp. 951- 61 (2001).
  60. R. M. Laine, J. Choi, I. Lee, "Organic-Inorganic Nanocomposites with Completely Defined Interfacial Interactions," Adv. Mater. , Vol. 13, pp. 800-3 (2001).
  61. R. Tamaki, Y. Tanaka, M. Z. Asuncion, J. Choi, R.M. Laine, "Octa(aminophenyl)silsesquioxane as a Nanoconstruction Site," ,” J. Am. Chem. Soc., Vol. 123, pp. 12416-7 (2001).
  62. R.O. R. Costa, W.L. Vasconcelos, R. Tamaki, and R.M. Laine, "Organic/Inorganic Nanocomposite Star Polymers via Atom Transfer Radical Polymerization of Methyl Methacrylate Using Octafunctional Silsesquioxane Cores," Macromol., Vol. 34, pp. 5398 -407 (2001).
  63. C. Zhang, R.M. Laine , "Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8. Octa (3-hydroxypropyldimethylsiloxy)octasilsesquioxane and its octamethacryl-ate derivative as potential precursors to hybrid nanocomposites," J. Am. Chem. Soc., Vol. 122, pp. 6979-88 (2000).
  64. H. Cheng, R. Tamaki, R.M. Laine, F. Babonneau, Y. Chujo, and D.R. Treadwell, "Neutral Alkoxysilanes from Silica," J. Am. Chem. Soc. , Vol. 122, pp. 10063-72 (2000).
  65. R. M. Laine, T. Hinklin, G. Williams, S.C. Rand, "Low-Cost Nanopowders for Phosphor and Laser Applications by Flame Spray Pyrolysis," in Mater. Sci. Forum, Scitec & Trans Tech. Publ., Zurich, Switzerland, Vol. 343-346, pp. 500-10 (2000).
  66. R.M. Laine, S.C. Rand, T. Hinklin, G. Williams, "Ultrafine Powders as Lasing Media," International patent application allowed. WO 0038282 H01S 20000629, (2000).
  67. G. Williams, S.C. Rand, T. Hinklin and R.M. Laine, "Blue and infrared laser action in strongly scattering Nd:alumina nanopowders," Proceedings of the Conference on Lasers and Electro-Optics (CLEO '99), May 23-28, Baltimore, MD, pp. 483 (1999).
  68. G. Williams, S.C. Rand, T. Hinklin and R.M. Laine, "Ultraviolet Laser Action in Strongly Scattering Ce:Alumina Nanopowders," Proceedings of the Conference on Lasers and Electro-Optics (CLEO '99), May 23-28, Baltimore, MD , pp. 90 (1999).
  69. M.C. Gravel, C. Zhang, M. Dinderman, R.M. Laine , "Octa(3-chloroammonium-propyl) octasilsesquioxane," J. Appl. Organomet. Chem. , Vol. 13, pp. 329-36 (1999).
  70. R.M. Laine, K. Waldner, C. Bickmore, D.R. Treadwell, "Ultrafine powders by flame spray pyrolysis," U.S. patent 5,958,361, Sept. 28, 1999, (1999).
  71. R.M. Laine, M. Asuncion, S. Baliat, N.L. Dias Filho, J. Harcup, A.C. Sutorik, L. Viculis, A.F. Yee, C. Zhang, and Q. Zhu, "Organic/Inorganic Molecular Hybrid Materials From Cubic Silsesquioxanes," in Organic/Inorganic Hybrid Materials, MRS Symp. Ser., Vol. 576, pp. 3-14, L. Klein, M. De Guire, F. Lorraine, J. Mark eds. Dec. 1999 (1999).
  72. A.C. Sutorik, S.S. Neo, T. Hinklin, R. Baranwal, D.R. Treadwell, R.Narayanan, R.M. Laine, "Synthesis of Ultrafine ”-Alumina Powders via Flame Spray Pyrolysis of Polymeric Precursors," J. Am. Ceram. Soc. , Vol. 81, pp. 1477-86 (1998).
  73. C. Zhang, F. Babonneau, C. Bonhomme, R.M. Laine, C.L. Soles, H.A. Hristov, A.F. Yee, "Highly Porous Polyhedral Silsesquioxane Polymers. Synthesis and Characterization," J. Am. Chem. Soc. , Vol. 120, pp. 8380-91 (1998).
  74. C.R. Bickmore, K.F. Waldner, R. Baranwal, T. Hinklin, D.R. Treadwell, R.M. Laine, "Ultrafine Titania by Flame Spray Pyrolysis of a Titanatrane Complex: Part I," J. Europ. Ceram. Soc., Vol. 18, pp. 287 (1998).
  75. E.K. Lin, C.R. Snyder, F.I. Mopsik, W.E. Wallace, W.L. W.C.X. Zhang, R. M. Laine, "Characterization of Epoxy-Functionalized Silsesquioxanes as Potential Underfill Encapsulants," in Organic/Inorganic Hybrid Materials, MRS Symp. Ser. , Vol. 519, pp. 15-20, R.M. Laine, C. Sanchez, C.J. Brinker, E. Giannelis eds. (1998).
  76. R.M. Laine, C. Zhang, A. Sellinger, L. Viculis, "Polyfunctional Cubic Silsesquioxanes as Building Blocks for Organic/Inorganic Hybrids," J. Appl. Organometallic Chem., Vol. 12, pp. 715-23 (1998).
  77. R.M. Laine, R. Baranwal, T. Hinklin, D. Treadwell, A. Sutorik, C.R. Bickmore, K. Waldner, S.S. Neo, "Making Nanosized Oxide Powders from Precursors by Flame Spray Pyrolysis," Novel Synthetic and Processing Routes to Ceramics, Uematsu, H. Otsuka, Eds., Key Engineering Materials , Vol. 159-160, pp. 17-24 (1998).
  78. D.R. Treadwell, A.C. Sutorik, S.S. Neo, R.M. Laine, R.C. Svedberg, "Synthesis of -Al2O3 Polymer Precursor and Ultrafine ”-Al2O3-Composition Powders,” in Synthesis and Characterization of Advanced Materials," ACS. Symp. Ser. , Vol. 681, pp. 146-157 (1997).
  79. A. Sellinger, R.M. Laine, "Silsesquioxanes as Synthetic Platforms. III. Photocurable, Liquid Epoxides as Inorganic/Organic Hybrid Precursors," Chem. Mater., Vol. 8, pp. 1592-3 (1996).
  80. A. Sellinger, R.M. Laine, "Silsesquioxanes as Synthetic Platforms. Thermally and Photo Curable Inorganic/Organic Hybrids," Macromol., Vol. 29, pp. 2327-30 (1996).
  81. C. Zhang, R.M. Laine, "Silsesquioxanes as Synthetic Platforms. II. Epoxy-Functionalized Inorganic/Organic Hybrid Species," J. Organomet. Chem. , Vol. 521, pp. 199-201 (1996).
  82. C.R. Bickmore, K.F. Waldner, D.R. Treadwell, R.M. Laine, "Ultrafine Spinel Powders by Flame Spray Pyrolysis of a Magnesium Aluminum Double Alkoxide," J. Am. Ceram. Soc. , Vol. 79, Issue 5, pp. 1419-23 (1996).
  83. A. Sellinger, R.M. Laine, "Coupling of Allyloxy and Propargyloxy Moieties with Hydridosilanes: Novel Liquid Crystalline Functionalized Silsesquioxanes," Am. Chem. Soc. Poly. Prprt. , Vol. 35, pp. 665-66 (1994).
  84. A. Sellinger, R.M. Laine, V. Chu, C. Viney, "Palladium and Platinum Catalyzed Coupling Reactions of Allyloxy Aromatics with Hydridosilanes and Hydridosiloxanes: Novel Liquid Crystalline/Organosilane Materials," J. Polymer Science, Part A: Polymer Chemistry, Vol. 32, pp. 3069-89 (1994).
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